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CH-kisloty
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Phosphorus : an outline of its chemistry, biochemistry, and uses
Doklady Chemistry, Vol. 380, Nos. 4–6, 2001, pp. 290–292. Translated from Doklady Akademii Nauk, Vol. 380, No. 5, 2001, pp. 645–648. Original Russian Text Copyright © 2001 by Shishkin, Mednikov, Anishchenko, No. CHEMISTRY C-Phosphorylated Acetimidates, a New Class of Organophosphorus C–H Acidic Compounds V. E. Shishkin, E. V. Mednikov, O. V. Anishchenko, and B. I. No Presented by Academician A. N. Konovalov May 10, 2001 Received June 20, 2001 Organophosphorus compounds are of great theoret- clic organophosphorus compounds and exhibit useful ical and practical importance. Some of their current biological activity [8, 9]. areas of application are in polymeric materials, biolog- In this research, we established for the first time that ically active compounds for medicine and agriculture, C-phosphorylated acetimidates, alkyl (dialkoxyphos- biological processes, lubricant additives, and complex- phoryl)acetimidates, exhibit C–H acidic properties forming agents [1, 2]. Reactions based on the use of the owing to the lability of the hydrogen atoms of the meth- C- H acidity of compounds have an important place ylene group disposed between electron-withdrawing among the various methods of preparing organophos- dialkoxyphosphoryl and imine groups. The revealed phorus compounds, as well as the products of organic reactions of the methylene group of these compounds
Doklady Chemistry – Springer Journals
Published: Oct 12, 2004
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