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C–C Bond Cleavage in Oxidation of Aliphatic Hydrocarbons under Mild Conditions in the VV/H2O2/AcOH System

C–C Bond Cleavage in Oxidation of Aliphatic Hydrocarbons under Mild Conditions in the... Doklady Chemistry, Vol. 378, Nos. 4–6, 2001, pp. 150–153. Translated from Doklady Akademii Nauk, Vol. 378, No. 5, 2001, pp. 639–643. Original Russian Text Copyright © 2001 by Gekhman, Stolyarov, Ershova, Moiseeva, Moiseev. CHEMISTRY This paper is dedicated to Prof. Brian James (University of British Columbia, Canada) in recognition of his outstanding contribution to homogeneous catalysis and inorganic chemistry C–C Bond Cleavage in Oxidation of Aliphatic Hydrocarbons under Mild Conditions in the V /H O /AcOH System 2 2 Corresponding Member of the RAS A. E. Gekhman*, I. P. Stolyarov**, N. V. Ershova*, N. I. Moiseeva**, and Academician I. I. Moiseev* Received March 5, 2001 The oxidation of alkanes by H O in all available should be noted that conventional inhibitors of free rad- 2 2 II III Fenton systems for hydroperoxide activation (Fe /Fe , ical chain reactions—BHT, p-benzoquinone, or IV V V VI II III V /V , Cr /Cr , Co /Co , etc.) results in alcohols anthracene derivatives (10 mol % of the substrate con- and ketones [1–3]. In this paper, we report on the oxi- centration)—have no effect on both the substrate con- dation of alkanes (using isooctane as an example) and sumption rate http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

C–C Bond Cleavage in Oxidation of Aliphatic Hydrocarbons under Mild Conditions in the VV/H2O2/AcOH System

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References (6)

Publisher
Springer Journals
Copyright
Copyright © 2001 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/A:1019230610870
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 378, Nos. 4–6, 2001, pp. 150–153. Translated from Doklady Akademii Nauk, Vol. 378, No. 5, 2001, pp. 639–643. Original Russian Text Copyright © 2001 by Gekhman, Stolyarov, Ershova, Moiseeva, Moiseev. CHEMISTRY This paper is dedicated to Prof. Brian James (University of British Columbia, Canada) in recognition of his outstanding contribution to homogeneous catalysis and inorganic chemistry C–C Bond Cleavage in Oxidation of Aliphatic Hydrocarbons under Mild Conditions in the V /H O /AcOH System 2 2 Corresponding Member of the RAS A. E. Gekhman*, I. P. Stolyarov**, N. V. Ershova*, N. I. Moiseeva**, and Academician I. I. Moiseev* Received March 5, 2001 The oxidation of alkanes by H O in all available should be noted that conventional inhibitors of free rad- 2 2 II III Fenton systems for hydroperoxide activation (Fe /Fe , ical chain reactions—BHT, p-benzoquinone, or IV V V VI II III V /V , Cr /Cr , Co /Co , etc.) results in alcohols anthracene derivatives (10 mol % of the substrate con- and ketones [1–3]. In this paper, we report on the oxi- centration)—have no effect on both the substrate con- dation of alkanes (using isooctane as an example) and sumption rate

Journal

Doklady Chemistry – Springer Journals

Published: Oct 12, 2004

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