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A SO2 sensor based on Na-β-Al2O3 interfaced with an auxiliary electrode of Na2SO4 formed in-situ and a solid mixture of Fe3O4, Fe2O3, 3Na2O·5Fe2O3 as the reference electrode was developed. The sensor displayed a good response to changes in the partial pressure of SO2 with a linear relationship between the measured emf and the logarithmic values of the partial pressure of SO2, as predicted by the Nernstian equation. Using an electron probe X-ray microanalyser, the formation of a Na2SO4 reaction layer was confirmed on the surface of Na-β-Al2O3 tube due to surface reaction with the SO2 gas.
Ionics – Springer Journals
Published: Mar 22, 2006
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