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Addition of bis(pentafluorophenyl)phosphinous acid to compounds with activated C=C bond as a method for the synthesis of first tertiary P,P-bis(pentafluorophenyl)phosphine oxides

Addition of bis(pentafluorophenyl)phosphinous acid to compounds with activated C=C bond as a... ISSN 00125008, Doklady Chemistry, 2010, Vol. 430, Part 1, pp. 18–23. © Pleiades Publishing, Ltd., 2010. Original Russian Text © N.G. Frolova, E.D. Savin, E.I. Goryunov, K.A. Lysenko, Yu.V. Nelyubina, P.V. Petrovskii, E.E. Nifant’ev, 2010, published in Doklady Akademii Nauk, 2010, Vol. 430, No. 2, pp. 202–207. CHEMISTRY Addition of Bis(pentafluorophenyl)phosphinous Acid to Compounds with Activated C=C Bond as a Method for the Synthesis of First Tertiary P,PBis(pentafluorophenyl)phosphine Oxides N. G. Frolova, E. D. Savin, E. I. Goryunov, K. A. Lysenko, Yu. V. Nelyubina, P. V. Petrovskii, and Corresponding Member of the RAS E. E. Nifant’ev Received July 29, 2009 DOI: 10.1134/S0012500810010052 Hydrophosphoryl compounds (HPCs) are very synthesis of P(V) compounds containing three P–C important synthons for the design of different classes bonds. On the contrary, bis(pentafluorophenyl)phos of organophosphorus compounds containing a pen phinous acid (BPFPPA) according to available litera tavalent fourcoordinate phosphorus atom [1]. ture data can exist in both tautomeric forms; it is rather Hydrophosphoryl compounds can be used to obtain stable both in the solid state and in solutions in organic organophosphorus compounds comprising solvents [5–7] and, therefore, is a rather promising starting compound for the design of tertiary bis(pen P(O)Hal, P(O)N, P(O)O, and P(O)C frag http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Addition of bis(pentafluorophenyl)phosphinous acid to compounds with activated C=C bond as a method for the synthesis of first tertiary P,P-bis(pentafluorophenyl)phosphine oxides

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References (10)

Publisher
Springer Journals
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500810010052
Publisher site
See Article on Publisher Site

Abstract

ISSN 00125008, Doklady Chemistry, 2010, Vol. 430, Part 1, pp. 18–23. © Pleiades Publishing, Ltd., 2010. Original Russian Text © N.G. Frolova, E.D. Savin, E.I. Goryunov, K.A. Lysenko, Yu.V. Nelyubina, P.V. Petrovskii, E.E. Nifant’ev, 2010, published in Doklady Akademii Nauk, 2010, Vol. 430, No. 2, pp. 202–207. CHEMISTRY Addition of Bis(pentafluorophenyl)phosphinous Acid to Compounds with Activated C=C Bond as a Method for the Synthesis of First Tertiary P,PBis(pentafluorophenyl)phosphine Oxides N. G. Frolova, E. D. Savin, E. I. Goryunov, K. A. Lysenko, Yu. V. Nelyubina, P. V. Petrovskii, and Corresponding Member of the RAS E. E. Nifant’ev Received July 29, 2009 DOI: 10.1134/S0012500810010052 Hydrophosphoryl compounds (HPCs) are very synthesis of P(V) compounds containing three P–C important synthons for the design of different classes bonds. On the contrary, bis(pentafluorophenyl)phos of organophosphorus compounds containing a pen phinous acid (BPFPPA) according to available litera tavalent fourcoordinate phosphorus atom [1]. ture data can exist in both tautomeric forms; it is rather Hydrophosphoryl compounds can be used to obtain stable both in the solid state and in solutions in organic organophosphorus compounds comprising solvents [5–7] and, therefore, is a rather promising starting compound for the design of tertiary bis(pen P(O)Hal, P(O)N, P(O)O, and P(O)C frag

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Doklady Chemistry – Springer Journals

Published: Jan 20, 2010

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