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About allyl methacrylate polymerization in the presence of PdCl2

About allyl methacrylate polymerization in the presence of PdCl2 ISSN 00125008, Doklady Chemistry, 2010, Vol. 435, Part 1, pp. 283–285. © Pleiades Publishing, Ltd., 2010. Original Russian Text © S.V. Kolesov, A.I. Vorob’eva, S.I. Kuznetsov, K.S. Svirskii, R.A. Zainullin, V.A. Dokichev, Yu.B. Monakov, 2010, published in Doklady Akademii Nauk, 2010, Vol. 435, No. 1, pp. 57–59. CHEMISTRY About Allyl Methacrylate Polymerization in the Presence of PdCl S. V. Kolesov, A. I. Vorob’eva, S. I. Kuznetsov, K. S. Svirskii, R. A. Zainullin, V. A. Dokichev, and Academician Yu. B. Monakov Received May 14, 2010 DOI: 10.1134/S0012500810110030 Allyl (meth)acrylates are known to be polymerized this difference is due to the electrondonating interac in a nitrogen atmosphere upon material initiation or tion of chromophore groups of AMA with the electron UV irradiation. In the initial reaction stages, soluble acceptor PdCl . Note that the color of the reaction polymers are formed, which are converted to insoluble mixture arising upon mixing the components changes form as polymerization goes to high degrees of conver during the process from brickred to yellowgreen. sion [1–3]. Examples of initiation of radical polymer The visually observed change of the color of the ization of acrylates by some metal halides, for exam AMA–PdCl mixture relative to AMA itself http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

About allyl methacrylate polymerization in the presence of PdCl2

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Publisher
Springer Journals
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500810110030
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Abstract

ISSN 00125008, Doklady Chemistry, 2010, Vol. 435, Part 1, pp. 283–285. © Pleiades Publishing, Ltd., 2010. Original Russian Text © S.V. Kolesov, A.I. Vorob’eva, S.I. Kuznetsov, K.S. Svirskii, R.A. Zainullin, V.A. Dokichev, Yu.B. Monakov, 2010, published in Doklady Akademii Nauk, 2010, Vol. 435, No. 1, pp. 57–59. CHEMISTRY About Allyl Methacrylate Polymerization in the Presence of PdCl S. V. Kolesov, A. I. Vorob’eva, S. I. Kuznetsov, K. S. Svirskii, R. A. Zainullin, V. A. Dokichev, and Academician Yu. B. Monakov Received May 14, 2010 DOI: 10.1134/S0012500810110030 Allyl (meth)acrylates are known to be polymerized this difference is due to the electrondonating interac in a nitrogen atmosphere upon material initiation or tion of chromophore groups of AMA with the electron UV irradiation. In the initial reaction stages, soluble acceptor PdCl . Note that the color of the reaction polymers are formed, which are converted to insoluble mixture arising upon mixing the components changes form as polymerization goes to high degrees of conver during the process from brickred to yellowgreen. sion [1–3]. Examples of initiation of radical polymer The visually observed change of the color of the ization of acrylates by some metal halides, for exam AMA–PdCl mixture relative to AMA itself

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Doklady Chemistry – Springer Journals

Published: Nov 26, 2010

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