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A Sm(III) Coordination Polymer Containing 2,5-Furandicarboxylic Acid: Crystal Structure and Recognition of Oxalate in Water

A Sm(III) Coordination Polymer Containing 2,5-Furandicarboxylic Acid: Crystal Structure and... The {[Sm2(FDC)2](FDC) · 10H2O}n complex, where H2FDC is a 2,5-furandicarboxylic acid, has been prepared by hydrothermal reaction and structurally characterized by X-ray single-crystal diffraction and elemental analyses. In the complex, each Sm3+ ion is nine-coordinated by four O atoms from two H2FDC ligands and five O atoms from five water molecules. Due to the crucial role of oxalate detection in food chemistry and clinical analysis, oxalate detecting properties were investigated in water by ultraviolet and visible spectroscopy. The results indicated that the complex is a potential candidate for oxalate detector in aqueous solution. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

A Sm(III) Coordination Polymer Containing 2,5-Furandicarboxylic Acid: Crystal Structure and Recognition of Oxalate in Water

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References (1)

Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Inc. 2020
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774520010289
Publisher site
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Abstract

The {[Sm2(FDC)2](FDC) · 10H2O}n complex, where H2FDC is a 2,5-furandicarboxylic acid, has been prepared by hydrothermal reaction and structurally characterized by X-ray single-crystal diffraction and elemental analyses. In the complex, each Sm3+ ion is nine-coordinated by four O atoms from two H2FDC ligands and five O atoms from five water molecules. Due to the crucial role of oxalate detection in food chemistry and clinical analysis, oxalate detecting properties were investigated in water by ultraviolet and visible spectroscopy. The results indicated that the complex is a potential candidate for oxalate detector in aqueous solution.

Journal

Crystallography Reports – Springer Journals

Published: Jan 25, 2020

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