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A Cobalt(II) Polymer Constructed by N,N '-Bis(3-Pyridinecarboxamide)-1,4-Benzene: Synthesis and Structural Characterization

A Cobalt(II) Polymer Constructed by N,N '-Bis(3-Pyridinecarboxamide)-1,4-Benzene: Synthesis and... Cobalt coordination polymer [Co(btec)0.5(3-bpcb)]n (H4btec is benzene-1,2,4,5-tetracarboxylic acid, 3-bpcb is N,N '-bis(3-pyridinecarboxamide)-1,4-benzene) has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The polymer crystallizes in the triclinic sp. gr. P\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$\bar {1}$$\end{document} with unit cell parameters a = 7.5989(3) Å, b = 9.4978(5) Å, c = 14.7638(7) Å, α = 93.116(2)°, β = 110.020(2)°, γ = 989.17(8)°, Z = 2. Cobalt(II) ions have octahedral coordination, linking different btec4− anions to form a two-dimensional layer, and 2D layers are associated into 3D networks via L-ligands. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

A Cobalt(II) Polymer Constructed by N,N '-Bis(3-Pyridinecarboxamide)-1,4-Benzene: Synthesis and Structural Characterization

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Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Inc. 2021. ISSN 1063-7745, Crystallography Reports, 2021, Vol. 66, No. 7, pp. 1286–1289. © Pleiades Publishing, Inc., 2021.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/s106377452107018x
Publisher site
See Article on Publisher Site

Abstract

Cobalt coordination polymer [Co(btec)0.5(3-bpcb)]n (H4btec is benzene-1,2,4,5-tetracarboxylic acid, 3-bpcb is N,N '-bis(3-pyridinecarboxamide)-1,4-benzene) has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The polymer crystallizes in the triclinic sp. gr. P\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$\bar {1}$$\end{document} with unit cell parameters a = 7.5989(3) Å, b = 9.4978(5) Å, c = 14.7638(7) Å, α = 93.116(2)°, β = 110.020(2)°, γ = 989.17(8)°, Z = 2. Cobalt(II) ions have octahedral coordination, linking different btec4− anions to form a two-dimensional layer, and 2D layers are associated into 3D networks via L-ligands.

Journal

Crystallography ReportsSpringer Journals

Published: Dec 1, 2021

References