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- Publisher
- IOS Press
- Copyright
- Copyright © 2016 IOS Press and the authors. All rights reserved
- ISSN
- 1878-5093
- DOI
- 10.3233/JBR-150108
- Publisher site
- See Article on Publisher Site
Abstract
BACKGROUND:Lingonberries have been associated with a range of potential bioactivities related to their polyphenol content and composition, in particular anthocyanin and proanthocyanidin derivatives.OBJECTIVES:The objective of this study was to examine the anthocyanin composition of extracts of lingonberry and related Vaccinium berries with respect to previously unidentified anthocyanin-like components.METHODS:Extracts were prepared from lingonberries, blueberries and a commercial cranberry juice product and examined by liquid chromatography mass spectroscopic techniques (LCMSn) before and after various fractionation steps.RESULTS:A range of discrete anthocyanin derivatives ethyl linked to (epi)catechin units were identified in lingonberry extracts using LC-MSn methods. Analogous derivatives were detected in similar blueberry extracts, and confirmed in cranberry juices.CONCLUSIONS:Through a combination of fractionation techniques and LCMSn analysis, this paper provides the first evidence that anthocyanin-epicatechin derivatives linked by ethyl bridges are present in lingonberries and in blueberries. These discrete components may be the smallest in a series of proanthocyanidin derivatives with terminal anthocyanins linked through ethyl groups which have previously been inferred in cranberries using mass spectrometric techniques.
Journal
Journal of Berry Research – IOS Press
Published: Jan 1, 2016