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Grazing-incidence small-angle X-ray scattering from a random rough surface: a self-consistent wavefunction approximation

Grazing-incidence small-angle X-ray scattering from a random rough surface: a self-consistent... An attempt is made to go beyond the distorted-wave Born approximation addressed to the grazing-incidence small-angle X-ray (GISAX) scattering from a random rough surface. The integral wave equation adjusted with the Green function formalism is applied. To find out an asymptotic solution of the non-averaged integral wave equation in terms of the Green function formalism, the theoretical approach based on a self-consistent approximation for the X-ray wavefunction is elaborated. Such an asymptotic solution allows one to describe the reflected X-ray wavefield everywhere in the scattering (, ) angular range, in particular below the critical angle cr for total external reflection ( is the grazing scattering angle with the surface, is the azimuth scattering angle; 0 is the grazing incidence angle). Analytical expressions for the reflected GISAX specular and diffuse scattering waves are obtained using the statistical model of a random Gaussian surface in terms of the r.m.s. roughness and two-point cumulant correlation function. For specular scattering the conventional Fresnel expression multiplied by the Debye-Waller factor is obtained. For the reflected GISAX diffuse scattering the intensity of the Rdif(, ) scan is written in terms of the statistical scattering factor and Fourier transform of the two-point cumulant correlation function. To be specific for isotropic solid surfaces, the statistical scattering factor and Fourier transform of the two-point cumulant correlation function parametrically depend on the root-mean-square roughness = 0 for = 0 and cumulant correlation length , respectively. The reflected Rdif(, ) scans are numerically simulated for the typical-valued {0, , } parameters array. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section A: Foundations of Crystallography International Union of Crystallography

Grazing-incidence small-angle X-ray scattering from a random rough surface: a self-consistent wavefunction approximation

Grazing-incidence small-angle X-ray scattering from a random rough surface: a self-consistent wavefunction approximation


Abstract

An attempt is made to go beyond the distorted-wave Born approximation addressed to the grazing-incidence small-angle X-ray (GISAX) scattering from a random rough surface. The integral wave equation adjusted with the Green function formalism is applied. To find out an asymptotic solution of the non-averaged integral wave equation in terms of the Green function formalism, the theoretical approach based on a self-consistent approximation for the X-ray wavefunction is elaborated. Such an asymptotic solution allows one to describe the reflected X-ray wavefield everywhere in the scattering (, ) angular range, in particular below the critical angle cr for total external reflection ( is the grazing scattering angle with the surface, is the azimuth scattering angle; 0 is the grazing incidence angle). Analytical expressions for the reflected GISAX specular and diffuse scattering waves are obtained using the statistical model of a random Gaussian surface in terms of the r.m.s. roughness and two-point cumulant correlation function. For specular scattering the conventional Fresnel expression multiplied by the Debye-Waller factor is obtained. For the reflected GISAX diffuse scattering the intensity of the Rdif(, ) scan is written in terms of the statistical scattering factor and Fourier transform of the two-point cumulant correlation function. To be specific for isotropic solid surfaces, the statistical scattering factor and Fourier transform of the two-point cumulant correlation function parametrically depend on the root-mean-square roughness = 0 for = 0 and cumulant correlation length , respectively. The reflected Rdif(, ) scans are numerically simulated for the typical-valued {0, , } parameters array.

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References (12)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2011 International Union of Crystallography
Subject
grazing-incidence small-angle X-ray scattering, GISAXS, rough surfaces, specular scattering, diffuse scattering
ISSN
0108-7673
eISSN
1600-5724
DOI
10.1107/S0108767311003357
pmid
21487178
Publisher site
See Article on Publisher Site

Abstract

An attempt is made to go beyond the distorted-wave Born approximation addressed to the grazing-incidence small-angle X-ray (GISAX) scattering from a random rough surface. The integral wave equation adjusted with the Green function formalism is applied. To find out an asymptotic solution of the non-averaged integral wave equation in terms of the Green function formalism, the theoretical approach based on a self-consistent approximation for the X-ray wavefunction is elaborated. Such an asymptotic solution allows one to describe the reflected X-ray wavefield everywhere in the scattering (, ) angular range, in particular below the critical angle cr for total external reflection ( is the grazing scattering angle with the surface, is the azimuth scattering angle; 0 is the grazing incidence angle). Analytical expressions for the reflected GISAX specular and diffuse scattering waves are obtained using the statistical model of a random Gaussian surface in terms of the r.m.s. roughness and two-point cumulant correlation function. For specular scattering the conventional Fresnel expression multiplied by the Debye-Waller factor is obtained. For the reflected GISAX diffuse scattering the intensity of the Rdif(, ) scan is written in terms of the statistical scattering factor and Fourier transform of the two-point cumulant correlation function. To be specific for isotropic solid surfaces, the statistical scattering factor and Fourier transform of the two-point cumulant correlation function parametrically depend on the root-mean-square roughness = 0 for = 0 and cumulant correlation length , respectively. The reflected Rdif(, ) scans are numerically simulated for the typical-valued {0, , } parameters array.

Journal

Acta Crystallographica Section A: Foundations of CrystallographyInternational Union of Crystallography

Published: Mar 10, 2011

Keywords: grazing-incidence small-angle X-ray scattering ; GISAXS ; rough surfaces ; specular scattering ; diffuse scattering .

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