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Two copper(II) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

Two copper(II) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and... AbstractTwo new copper(II) complexes, {[Cu(bipmo)(npa)]}n (1) and {[Cu(bipmo)(pa)]}n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of neutral metal aromatic carboxylate layers, which are pillared by the weak interactions to generate 3D architectures. The topological structures of 1 and 2 are uninodal nets based on 4-connected nodes with the Schläfli symbol of (65·8). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B de Gruyter

Two copper(II) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

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References (8)

Publisher
de Gruyter
Copyright
©2017 Walter de Gruyter GmbH, Berlin/Boston
ISSN
0932-0776
eISSN
1865-7117
DOI
10.1515/znb-2016-0225
Publisher site
See Article on Publisher Site

Abstract

AbstractTwo new copper(II) complexes, {[Cu(bipmo)(npa)]}n (1) and {[Cu(bipmo)(pa)]}n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of neutral metal aromatic carboxylate layers, which are pillared by the weak interactions to generate 3D architectures. The topological structures of 1 and 2 are uninodal nets based on 4-connected nodes with the Schläfli symbol of (65·8).

Journal

Zeitschrift für Naturforschung Bde Gruyter

Published: Apr 1, 2017

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