Access the full text.
Sign up today, get DeepDyve free for 14 days.
(2004)
Russ. Chem. Bull
(2005)
Chem. Phys. Lett
(1980)
Austr. J. Chem
(1965)
J. Phys. Chem
(2006)
Phys. Rev. B
(1966)
Trans. Faraday Soc
(2001)
Phys. Chem. Chem. Phys
(2003)
J. Electroanal. Chem
W. MacKnight (1976)
Macromolecules.Science, 191 4233
(1985)
J. Am. Chem. Soc
(2006)
Photochem. Photobiol. A:Chem
M. Konshin, P. Petyunin (1971)
HeterocyclesPharmaceutical Chemistry Journal, 5
(1989)
Mol. Cryst. Liq. Cryst
(1994)
Prog. Inorg. Chem
(1969)
Mol. Phys
(2006)
Chem. Commun
(2002)
Angew. Chem. Int. Ed
(1997)
Z. Kristallogr
A. Bogatskii, S. Andronati, Z. Zhilina, O. Kobzareva, P. Sharbatyan, R. Ivanova, T. Chumachenko (1975)
Zh. Obshch. Khim.
Galvinols are interesting, sterically hindered compounds that serve as precursors for the generation of stable galvinoxyl radicals. In order to elucidate their basic structural chemistry and the influence of steric effects on their conformation a comparative analysis of several galvinol derivatives was undertaken. The aryl and quinoid subunits could clearly be identified, and substituents at the connecting methine bridge were found to influence the conformation of the molecules. As a result of the sterically hindered residues the molecules pack mainly through weak van der Waals interactions without formation of hydrogen bonds. The observation of different crystal forms and packing for galvinols and their conformational flexibility will impact current solid-state applications and provides unambiguous structural data for theoretical calculations.
Zeitschrift für Naturforschung B – de Gruyter
Published: Nov 1, 2012
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.