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(1978)
Less-Common Met
(2008)
Intermetallic Chemistry
S. Thimmaiah, G. Miller (2015)
Influence of Valence Electron Concentration on Laves Phases: Structures and Phase Stability of Pseudo-Binary MgZn2-xPdxZeitschrift für anorganische und allgemeine Chemie, 641
Shahrad Amerioun, S. Simak, U. Häussermann (2003)
Laves-phase structural changes in the system CaAl2-xMgx.Inorganic chemistry, 42 5
V. Petříček, M. Dušek, L. Palatinus (2014)
Crystallographic Computing System JANA2006: General featuresZeitschrift für Kristallographie - Crystalline Materials, 229
R. Nesper, G. Miller (1993)
A covalent view of chemical bonding in Laves phases CaLixAl2 − xJournal of Alloys and Compounds, 197
E. Ganglberger, H. Nowotny, F. Benesovsky (1965)
Ternre Phasen mit MgZn2?Ty: Kurze MitteilungMonatshefte Fur Chemie, 96
Lukas Heletta, S. Matar, R. Pöttgen (2018)
ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGaZeitschrift für Naturforschung B, 74
Sebastian Stein, T. Block, Steffen Klenner, Lukas Heletta, R. Pöttgen (2018)
Equiatomic iron-based tetrelides TFeSi and TFeGe (T = Zr, Nb, Hf, Ta) – A 57Fe Mössbauer-spectroscopic studyZeitschrift für Naturforschung B, 74
W. Taylor (1954)
Variations in the anorthite structure: a noteActa Crystallographica, 7
Mihaela Bojin, R. Hoffmann (2003)
The RE M E PhasesHelvetica Chimica Acta, 86
M. Dryś (1980)
Phase equilibria in the niobium-gallium-manganese system at 900 °CJournal of The Less Common Metals, 75
S. Seidel, R. Pöttgen (2017)
Yb6Ir5Ga7 – A MgZn2 SuperstructureZeitschrift für anorganische und allgemeine Chemie, 643
(1969)
Proc
(2016)
Intermetallics: Structures
R. Hoffmann, R. Pöttgen (2001)
AlB2-related intermetallic compounds – a comprehensive view based on group-subgroup relationsZeitschrift für Kristallographie - Crystalline Materials, 216
A. Ormeci, A. Simon, Y. Grin (2010)
Structural topology and chemical bonding in Laves phases.Angewandte Chemie, 49 47
X. Yan, A. Grytsiv, P. Rogl, H. Schmidt, G. Giester, A. Saccone, Xing-Qiu Chen (2009)
Laves phases in the ternary systems Ti–{Pd, Pt}–AlIntermetallics, 17
M. Teslyuk, V. Markiv, E. Gladyshevskii (1964)
Ternary laves phases in Nb(Ta)-Fe(Co, Ni)-Ga(Ge) systemsJournal of Structural Chemistry, 5
A. Keitz, G. Sauthoff (2002)
Laves phases for high temperatures—Part II: Stability and mechanical propertiesIntermetallics, 10
Fabian Eustermann, A. Pominov, R. Pöttgen (2018)
Rare Earth (RE ) Gallides with Closely Related Compositions: RE IrGa and RE 6 Ir5 Ga7Zeitschrift für anorganische und allgemeine Chemie
P. Villars, K. Cenzual, W. Pearson (2007)
Pearson's crystal data : crystal structure database for inorganic compounds
R. Pöttgen (2014)
Coloring, Distortions, and Puckering in Selected Intermetallic Structures from the Perspective of Group‐Subgroup RelationsZeitschrift für anorganische und allgemeine Chemie, 640
Lukas Heletta, S. Seidel, C. Benndorf, H. Eckert, R. Pöttgen (2017)
Gallium-containing Heusler phases ScRh2Ga, ScPd2Ga, TmRh2Ga and LuRh2Ga – magnetic and solid state NMR-spectroscopic characterizationZeitschrift für Naturforschung B, 72
S. Seidel, O. Janka, C. Benndorf, Bernhard Mausolf, F. Haarmann, H. Eckert, Lukas Heletta, R. Pöttgen (2017)
Ternary rhombohedral Laves phases RE2Rh3Ga (RE = Y, La–Nd, Sm, Gd–Er)Zeitschrift für Naturforschung B, 72
F. Hulliger (1996)
On new rare-earth compounds LnIrGa and LnRhGaJournal of Alloys and Compounds, 239
B. Verbeek, H. Rompa, P. Larsen, M. Methfessel, F. Mueller (1983)
Mixed states in RhA1, RhGa, and RhIn studied by photoemission spectroscopy and band-structure calculationsPhysical Review B, 28
F. Stein, M. Palm, G. Sauthoff (2004)
Structure and stability of Laves phases. Part I. Critical assessment of factors controlling Laves phase stabilityIntermetallics, 12
J. Jorda, J. Muller, H. Braun, C. Susz (1987)
Phase relationships in the ternary system Ti-Au-Al at 775 KJournal of The Less Common Metals, 134
E. Parthé, L. Gelato, B. Chabot, M. Penzo, K. Cenzual, R. Gladyshevskii (1993)
TYPIX Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types
(2002)
U . Häussermann
E. Hovestreydt, N. Engel, K. Klepp, B. Chabot, E. Parthé (1982)
Equiatomic ternary rare earth-transition metal silicides, germanides and gallidesJournal of The Less Common Metals, 85
(1978)
Markiv, Dopov
V. Compton (1958)
Crystal structures of MgRh and ScRhActa Crystallographica, 11
Thomas Harmening, L. Wüllen, H. Eckert, U. Rodewald, R. Pöttgen (2010)
Sc4Pt7Si2 – An Intergrowth Structure of ScPtSi and ScPt Related SlabsZeitschrift für anorganische und allgemeine Chemie, 636
A. Vermeulen, S. Ambler, G. Bumgardner, Eldon Misfeldt, Jim Thompson (1998)
The Elements
O. Osters, T. Nilges, M. Schöneich, P. Schmidt, J. Rothballer, Florian Pielnhofer, R. Weihrich (2012)
Cd4Cu7As, the first representative of a fully ordered, orthorhombically distorted MgCu2 Laves phase.Inorganic chemistry, 51 15
C. Shoemaker, D. Shoemaker (1965)
A TERNARY ALLOY WITH PBCL2-TYPE STRUCTURE: TINISI(E),Acta Crystallographica, 18
R. Poettgen, W. Jeitschko (1991)
Scandium carbide, Sc3C4, a carbide with C3 units derived from propadieneInorganic Chemistry, 30
D. Noréus, L. Eriksson, L. Göthe, P. Werner (1985)
Structure determination of Mg2SiNi3Journal of The Less Common Metals, 107
K. Yvon, W. Jeitschko, E. Parthé (1977)
LAZY PULVERIX, a computer program, for calculating X‐ray and neutron diffraction powder patternsJournal of Applied Crystallography, 10
J. Donohue (1974)
The structures of the elements
G. Nuspl, K. Polborn, J. Evers, G. Landrum, R. Hoffmann (1996)
The Four-Connected Net in the CeCu(2) Structure and Its Ternary Derivatives. Its Electronic and Structural Properties.Inorganic chemistry, 35 24
R. Pöttgen, D. Johrendt (2014)
Intermetallics: Synthesis, Structure, Function
L. Palatinus, G. Chapuis (2007)
SUPERFLIP– a computer program for the solution of crystal structures by charge flipping in arbitrary dimensionsJournal of Applied Crystallography, 40
K. Osamura, Y. Murakami (1978)
Crystal structures of CuSnMg and Cu4SnMg ternary compoundsJournal of The Less Common Metals, 60
(2017)
WinNormos for Igor6 (Version for Igor 6.2 or above: 22.02.2017)
R. Johnston, R. Hoffmann (1992)
Structure-Bonding Relationships in the Laves Phases†Zeitschrift für anorganische und allgemeine Chemie, 616
L. Booher, E. Callison (1939)
The Minimum Vitamin-A Requirements of Normal Adults II. The Utilization of Carotene as Affected by Certain Dietary Factors and Variations in Light ExposureOne FigureJournal of Nutrition, 18
AbstractA series of ternary transition metal gallides around the equiatomic composition have been synthesized from the elements by arc-melting and subsequent annealing. The compounds crystallize with site occupancy variants of the hexagonal Laves phase MgZn2, with the hexagonal ZrBeSi or the orthorhombic TiNiSi type. All samples have been characterized on the basis of their lattice parameters, determined by X-ray powder diffraction (Guinier technique). The structures of NbCr1.58Ga0.42 and NbFe1.51Ga0.49 (MgZn2 type, P63/mmc), NbRhGa (ZrBeSi type, P63/mmc), and ScNiGa, ScPtGa and ScAuGa (TiNiSi type, Pnma) were refined from single crystal X-ray diffractometer data. The ScPtGa and ScAuGa crystals showed trilling formation. Mixed site occupancies were only observed in the Laves phases while all other crystals were well ordered. A striking structural motif of NbRhGa is the formation of niobium chains (264 pm Nb–Nb) along the c axis. Several gallides were magnetically characterized. They are Pauli paramagnets. The two crystallographically independent iron sites in the Laves phase TaFeGa could be distinguished in the 57Fe Mössbauer spectrum. The isomer shifts of 0.06(3) (Fe1) and –0.02(3) (Fe2) mm s−1 indicate metallic iron.
Zeitschrift für Naturforschung B – de Gruyter
Published: Mar 26, 2019
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