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- Publisher
- de Gruyter
- Copyright
- © 2020 Walter de Gruyter GmbH, Berlin/Boston
- ISSN
- 0932-0776
- eISSN
- 1865-7117
- DOI
- 10.1515/znb-2019-0211
- Publisher site
- See Article on Publisher Site
Abstract
AbstractRe(CO)5Cl reacts with salophenH2 to yield Re(I)2(salophenH)(CO)6Cl. A crystal structure determination has shown that this binuclear complex contains two Re(CO)3 fragments which are bridged by a chloride and a heavily constrained salophenH– anion as ligands. Under ambient conditions in solution and in the solid state, the complex displays an orange emission which originates from the lowest-energy IL/MLCT triplet. In solution, this phosphorescence is completely quenched by oxygen.
Journal
Zeitschrift für Naturforschung B – de Gruyter
Published: Dec 16, 2020