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C. Paraschiv, M. Andruh, Y. Journaux, Z. Ẑák, N. Kyritsakas, L. Ricard (2006)
Trinuclear magnetic clusters based on cyanide metal complexes: synthesis, crystal structures, and magnetic properties of four new [MnII2MIII] complexes (M = Cr, Fe, Co)Journal of Materials Chemistry, 16
J. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, C. Mathonière (2004)
Reversible photoinduced magnetic properties in the heptanuclear complex [Mo(IV)(CN)(2)(CN--CuL)(6)](8+): a photomagnetic high-spin molecule.Angewandte Chemie, 43 41
G. Rombaut, S. Golhen, L. Ouahab, C. Mathonière, O. Kahn (2000)
Structural and photomagnetic studies of a 1-D bimetallic chain [MnII2(L)2(H2O)][MoIV(CN)8]·5H2O (L = macrocycle): analogy with the photo-oxidation of K4[MoIV(CN)8]·2H2OJournal of The Chemical Society-dalton Transactions
Maliheh Mousavi, V. Béreau, C. Desplanches, C. Duhayon, J. Sutter (2010)
Substantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n.Chemical communications, 46 40
AbstractBy using K4[Mo(CN)8] and [Ni(L)(H2O)2][ClO4]2 as reagents (L = 2,12-dimethyl-3,7,11,17-tetraazabicyclo [11.3.1]heptadeca-1(17),13,15-triene), a new cyanide-bridged Mo–Ni complex containing the building blocks [Ni(H2O)(L)]2+ and [Ni(L)]2+ bridged by [Mo(CN)8]4− units has been obtained. The complex with the formula {[Ni(H2O)(L)][Ni(L)][Mo(CN)8]}6 · 36H2O · 2CH3OH (1) was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The structure determination reveals an octadecanuclear cluster in the form of a 36-membered macrocycle, in which the largest intramolecular W···W and Ni···Ni distances are 16.5 and 14.4 Å, respectively, indicating that complex 1 is a nanosized molecular wheel. Investigation of its magnetic properties has shown weak antiferromagnetic coupling between the adjacent Ni(II) ions bridged by the diamagnetic [Mo(CN)8]4− ions.
Zeitschrift für Naturforschung B – de Gruyter
Published: Aug 1, 2015
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