Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]

Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and... AbstractTwo new sodium borates [Na2(H2O)3][B5O8(OH)2] (1) and Na[enH2][B7O10(OH)4] (2) have been synthesized and their structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system space group C2/c with a = 11.118(2), b = 16.442(2), c = 13.572(2) Å, β =112.90(1)°, V = 2285.4(5) Å3, and Z = 4. Compound 2 crystallizes in the triclinic space group P1̅, with a = 7.4974(9), b = 8.349(2), c = 11.746(2), α = 93.98(1), β = 97.25(1), γ = 101.18(1)°, V = 712.2(2) Å3, and Z = 2. Compound 1 possesses {Na2B5O8(OH)2·3H2O}n chains which form through the connection of the fundamental building blocks (FBBs) [B5O8(OH)2]2– by sharing Na+ ions, while compound 2 has infinite {Na[B7O10(OH)4]}n sheets which form via the connection of the FBBs [B7O10(OH)4]3– by common Na+ ions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B de Gruyter

Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]

Download PDF
7 pages

Loading next page...
 
/lp/de-gruyter/syntheses-and-crystal-structures-of-two-new-sodium-borates-na2-h2o-3-VStP2IYuVR

References (11)

Publisher
de Gruyter
Copyright
©2016 by De Gruyter
ISSN
0932-0776
eISSN
1865-7117
DOI
10.1515/znb-2015-0072
Publisher site
See Article on Publisher Site

Abstract

AbstractTwo new sodium borates [Na2(H2O)3][B5O8(OH)2] (1) and Na[enH2][B7O10(OH)4] (2) have been synthesized and their structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system space group C2/c with a = 11.118(2), b = 16.442(2), c = 13.572(2) Å, β =112.90(1)°, V = 2285.4(5) Å3, and Z = 4. Compound 2 crystallizes in the triclinic space group P1̅, with a = 7.4974(9), b = 8.349(2), c = 11.746(2), α = 93.98(1), β = 97.25(1), γ = 101.18(1)°, V = 712.2(2) Å3, and Z = 2. Compound 1 possesses {Na2B5O8(OH)2·3H2O}n chains which form through the connection of the fundamental building blocks (FBBs) [B5O8(OH)2]2– by sharing Na+ ions, while compound 2 has infinite {Na[B7O10(OH)4]}n sheets which form via the connection of the FBBs [B7O10(OH)4]3– by common Na+ ions.

Journal

Zeitschrift für Naturforschung B – de Gruyter

Published: Jan 1, 2016

There are no references for this article.