Structural Chemistry of Titanium Alkoxides Substituted by the Chelating Bidentate Ligands Isoeugenolate or 2-Aminoethanolate
Structural Chemistry of Titanium Alkoxides Substituted by the Chelating Bidentate Ligands...
Fric, Helmut; Kogler, Franz René; Puchberger, Michael; Schubert, Ulrich
2004-12-01 00:00:00
AbstractThe compounds [Ti(OPr)3(isoeugenolate)]2 and [Ti(OR)3(OCH2CH2NH2)]2(R = iPr, Et), obtained by reaction of titanium alkoxides with isoeugenol (2-methoxy-4-propenylphenol) or 2- aminoethanol, are centrosymmetric dimers with a central Ti2(μ2-OR)2 unit. The isoeugenolate and 2-aminoethanolate ligands are chelating, with the uncharged donor group (OR or NH2, respectively) axial to the Ti2(μ2-OR)2 ring.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngZeitschrift für Naturforschung Bde Gruyterhttp://www.deepdyve.com/lp/de-gruyter/structural-chemistry-of-titanium-alkoxides-substituted-by-the-negUvlZiE0
Structural Chemistry of Titanium Alkoxides Substituted by the Chelating Bidentate Ligands Isoeugenolate or 2-Aminoethanolate
AbstractThe compounds [Ti(OPr)3(isoeugenolate)]2 and [Ti(OR)3(OCH2CH2NH2)]2(R = iPr, Et), obtained by reaction of titanium alkoxides with isoeugenol (2-methoxy-4-propenylphenol) or 2- aminoethanol, are centrosymmetric dimers with a central Ti2(μ2-OR)2 unit. The isoeugenolate and 2-aminoethanolate ligands are chelating, with the uncharged donor group (OR or NH2, respectively) axial to the Ti2(μ2-OR)2 ring.
Journal
Zeitschrift für Naturforschung B
– de Gruyter
Published: Dec 1, 2004
Keywords: Key words Titanium Alkoxide Derivatives; Chelating Ligands; Organically Modified Metal Alkoxides
To get new article updates from a journal on your personalized homepage, please log in first, or sign up for a DeepDyve account if you don’t already have one.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.