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Optically Active Transition Metal Compounds, 136 (1). An Octahedral Molybdenum Complex (P-P’)Mo(CO) 4 with a Chiral Secondary Phosphorus Atom

Optically Active Transition Metal Compounds, 136 (1). An Octahedral Molybdenum Complex... Abstract Reaction of (η 6 -C 6 H 5 CH 3 )Mo(CO) 3 with the easily accessible chiral chelate ligand P,P,Pʹ-tris- ((+)-9-phenyldeltacyclan-8-yl)-1,2-bis(phosphanyl)benzene P-P’ afforded the octahedral molybdenum carbonyl derivate (P-P’)Mo(CO) 4 1 as a diastereomer mixture 1a (74%) and 1b (26%). Crystallization gave single crystals of (SP)-(P-P’)Mo(CO) 4 1a. The X-ray structure analysis of compound 1a revealed the formation of an unusual triple-decker π-stack in the solid state. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B de Gruyter

Optically Active Transition Metal Compounds, 136 (1). An Octahedral Molybdenum Complex (P-P’)Mo(CO) 4 with a Chiral Secondary Phosphorus Atom

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Publisher
de Gruyter
Copyright
Copyright © 2004 by the
ISSN
0932-0776
eISSN
1865-7117
DOI
10.1515/znb-2004-0803
Publisher site
See Article on Publisher Site

Abstract

Abstract Reaction of (η 6 -C 6 H 5 CH 3 )Mo(CO) 3 with the easily accessible chiral chelate ligand P,P,Pʹ-tris- ((+)-9-phenyldeltacyclan-8-yl)-1,2-bis(phosphanyl)benzene P-P’ afforded the octahedral molybdenum carbonyl derivate (P-P’)Mo(CO) 4 1 as a diastereomer mixture 1a (74%) and 1b (26%). Crystallization gave single crystals of (SP)-(P-P’)Mo(CO) 4 1a. The X-ray structure analysis of compound 1a revealed the formation of an unusual triple-decker π-stack in the solid state.

Journal

Zeitschrift für Naturforschung Bde Gruyter

Published: Aug 1, 2004

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