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/lp/de-gruyter/novel-guanidine-quinoline-hybrid-ligands-and-the-application-of-their-w05IOnB0Mn
References (6)
-
(2007)
Herres-Pawlis in Renewable and Sustainable Polymers -
(2008)
PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht (The Netherlands -
(1996)
Praxis der Organischen Chemie -
(2008)
Novel Guanidine-Quinoline Hybrid Ligands Vaca, D -
J. Mark (2009)
Polymer Data Handbook -
(2008)
SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Göttingen (Germany) 1997
- Publisher
- de Gruyter
- Copyright
- Copyright © 2012 by the
- ISSN
- 0932-0776
- eISSN
- 1865-7117
- DOI
- 10.1515/znb-2012-0405
- Publisher site
- See Article on Publisher Site
Abstract
The syntheses of the three new guanidine-quinoline hybrid ligands TMGmqu, DMEGmqu and TMG t bqu are reported. Zinc chlorido and triflato complexes with these ligands were obtained and structurally characterised by X-ray crystallography. In the chlorido complexes the zinc atom is coordinated by two chlorido ligands and the bidentate guanidine ligand in a distorted tetrahedron. Using zinc triflate, tetrahedral bis(chelate) complexes are formed, and the triflate anions serve only for charge compensation. All reported complexes show activity in the polymerisation of rac-lactide, with the chlorido complexes only showing a poor activity. With the bis(chelate) triflato complexes a high polymerisation activity with a slight heterotactic bias was observed. Kinetic studies reveal a firstorder chain growth reaction for the lactide polymerisation with all complexes.
Journal
Zeitschrift für Naturforschung B – de Gruyter
Published: Apr 1, 2012