Access the full text.
Sign up today, get DeepDyve free for 14 days.
Michael Langenmaier, Tobias Rackl, Dirk Johrendt, Caroline Röhr (2018)
Alkali chalcogenido ortho manganates(II) A6MnQ4 (A=Rb, Cs; Q=S, Se, Te)Zeitschrift für Naturforschung B, 73
L. Gelato, E. Parthé (1987)
STRUCTURE TIDY– a computer program to standardize crystal structure dataJournal of Applied Crystallography, 20
M. Aroyo, J. Perez-Mato, C. Capillas, E. Kroumova, S. Ivantchev, G. Madariaga, A. Kirov, H. Wondratschek (2006)
Bilbao Crystallographic Server: I. Databases and crystallographic computing programsZeitschrift für Kristallographie - Crystalline Materials, 221
W. Bronger (1981)
Ternary Sulfides: Model Compounds for the Correlation of Crystal Structure and Magnetic PropertiesAngewandte Chemie, 20
Johanna Heine, S. Dehnen (2008)
Synthesis and Characterization of the First Salts of the ortho‐Selenidoindate Anion [InSe4]5−Zeitschrift für anorganische und allgemeine Chemie, 634
M. Harrison, M. Francesconi (2011)
Mixed-metal one-dimensional sulfides—A class of materials with differences and similarities to oxidesCoordination Chemistry Reviews, 255
Michael Langenmaier, S. Wissinger, C. Röhr (2020)
K 5 [InSe 4 ] and K 12 [InS 4 ] 2 (S): New Alkali Chalcogenido Indates with [In Q 4 ] 5 – orthoZeitschrift für anorganische und allgemeine Chemie
U. Müller (2004)
Kristallographische Gruppe‐Untergruppe‐Beziehungen und ihre Anwendung in der KristallchemieZeitschrift für anorganische und allgemeine Chemie, 630
M. Schwarz, P. Stüble, K. Köhler, C. Röhr (2020)
New mixed-valent alkali chain sulfido ferrates A1+x[FeS2] (A = K, Rb, Cs; x = 0.333–0.787)Zeitschrift für Kristallographie - Crystalline Materials, 235
L. Krause, R. Herbst‐Irmer, G. Sheldrick, D. Stalke (2015)
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determinationJournal of Applied Crystallography, 48
B. Eisenmann, A. Hofmann (1991)
Crystal structure of pentasodium tetrathioindate(III), Na5InS4Zeitschrift für Kristallographie - Crystalline Materials, 197
(2006)
New sodium-rich mixed Mn/In chalcogenido metallates
(2004)
Z . Anorg
P. Stüble, S. Peschke, D. Johrendt, C. Röhr (2018)
Na7[Fe2S6], Na2[FeS2] and Na2[FeSe2]: New ‘Reduced’ Sodium Chalcogenido FerratesJournal of Solid State Chemistry, 258
Michael Langenmaier, C. Röhr (2019)
The new sodium tellurido manganates(II) Na2Mn2Te3, Na2Mn3Te4, Na2AMnTe3 (A=K, Rb), and NaCsMnTe2Zeitschrift für Naturforschung B, 74
M. Schwarz, C. Röhr (2015)
Cs8[Fe4S10] and Cs7[Fe4S8], two new sulfido ferrates with different tetrameric anions.Inorganic chemistry, 54 3
P. Stüble, A. Berroth, C. Röhr (2016)
Synthesis and crystal structure of new K and Rb selenido/tellurido ferrate cluster compoundsZeitschrift für Naturforschung B, 71
P. Stüble, Jan Kägi, C. Röhr (2016)
Synthesis, crystal and electronic structure of the new sodium chain sulfido cobaltates(II), Na3CoS3 and Na5[CoS2]2(Br)Zeitschrift für Naturforschung B, 71
K. Yvon, W. Jeitschko, E. Parthé (1977)
LAZY PULVERIX, a computer program, for calculating X‐ray and neutron diffraction powder patternsJournal of Applied Crystallography, 10
(1987)
CCDC 1996103 ( Na 12 MnIn 2 S 10 ) and 1996104 ( Na 12 MnIn 2 Se 10 ) contain the supplementary crystallographic data for this paper
P. Stüble, C. Röhr (2017)
Cs[FeSe2], Cs3[FeSe2]2, and Cs7[Fe4Se8]: Missing Links of Known Chalcogenido Ferrate SeriesZeitschrift für anorganische und allgemeine Chemie, 643
M. Schwarz, M. Haas, C. Röhr (2013)
Die neuen Alkalimetall‐Sulfidoferrate K9[FeIIIS4](S2)S, (K/Rb)6[FeIII2S6], Rb8[FeIII4S10] und K7[FeII/IIIS2]5Zeitschrift für anorganische und allgemeine Chemie, 639
W. Bronger, P. Müller (1997)
The magnetochemical characterisation of the bonding features in ternary chalcogenides of manganese, iron and cobalt with low dimensional structural unitsJournal of Alloys and Compounds, 246
T. Papenfuhs (1982)
2‐Aminobenzothiazole durch oxidative Cyclisierung von Arylthioharnstoffen mit SulfinylchloridAngewandte Chemie, 21
L. Finger, M. Kroeker, B. Toby (2007)
DRAWxtl, an open-source computer program to produce crystal structure drawingsJournal of Applied Crystallography, 40
W. Bronger, M. Kimpel, D. Schmitz (1982)
Cs7Fe4Te8, A Compound with [Fe4Te8] ClustersAngewandte Chemie, 21
M. Schwarz, P. Stüble, C. Röhr (2017)
Rubidium chalcogenido diferrates(III) containing dimers [Fe2Q6]6− of edge-sharing tetrahedra (Q=O, S, Se)Zeitschrift für Naturforschung B, 72
AbstractThe sodium-rich sulfido and selenido metallates Na12MnIn2Q10 (Q = S/Se) were synthesized in pure phase from melts composed of stoichiometric quantities of the manganese monochalcogenides MnQ, elemental indium and the chalcogens together with either Na2S (Q = S) or elemental sodium (Q = Se) as starting material. The samples were heated up to maximum temperatures of 1000/900 °C under an argon atmosphere; crystallization was achieved by slow cooling rates of 10 K h−1. The two isotypic compounds (monoclinic, space group P21/m, a = 678.26(2)/698.85(10), b = 2202.77(7)/2298.7(3), c = 766.39(3)/800.59(13) pm, β = 90.232(2)/90.147(5)°, Z = 2, R1 = 0.0516/0.0575) crystallize in a new structure type. According to the division of the formula as Na12[InQ4][MnInQ6] the salts contain ortho indate anions [InIIIQ4]5− besides hetero-bimetallic dimers [MnIIInIIIQ6]7−, which consist of two edge-sharing [MQ4] tetrahedra. The seven crystallographically different sodium cations exhibit an either tetrahedral or octahedral coordination by the chalcogen atoms. Thus, the overall structure of the salt is best described by a hexagonal close packing of the sulfide/selenide anions, in which the octahedral voids of every second interlayer section are fully occupied by the (overall 5/f.u.) Na+ positions with CN = 6. In the other half of the interlayer sheets, all tetrahedral voids (overall 10/f.u.) are occupied by the seven CN = 4 Na+ cations, one In3+ of the ortho anion and the two Mn2+/In3+ cations (which statistically occupy one crystallographic site). This structure relation is also verified by a Bärnighausen group-subgroup tree connecting the h.c.p. (Mg type) aristotype (with its tetrahedral and octahedral voids) by an overall index of 60 with the structure of the two title compounds.
Zeitschrift für Naturforschung B – de Gruyter
Published: Nov 26, 2020
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.