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Methyl(trifluormethyl)haIogensulfonium-Salze [1] Halogen = F, CI, Br, I Methyl(trifluoromethyl)halosulfonium Salts [1] / Methyl(trifluoromethyl)halosulfonium Salts [1] Halogen = F, Cl, Br, I

Methyl(trifluormethyl)haIogensulfonium-Salze [1] Halogen = F, CI, Br, I... AbstractThe preparation and spectroscopic characterization of the halosulfonium salts CH3(CF3)SHal+ A-(Hal = F, Cl, Br, I, A- = AsF6-, SbF6-, SbCl 6-) is reported. The compounds are synthesized by the reaction of the sulfane CH3SCF3 with XeF+MF6-, Cl2F+AsFf6-, Cl2/AsF5, Cl2/SbCl5 , Br2/AsF5 , or I3+MF6- (M = As, Sb), resp., at low temperatures. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B de Gruyter

Methyl(trifluormethyl)haIogensulfonium-Salze [1] Halogen = F, CI, Br, I Methyl(trifluoromethyl)halosulfonium Salts [1] / Methyl(trifluoromethyl)halosulfonium Salts [1] Halogen = F, Cl, Br, I

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Publisher
de Gruyter
Copyright
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
ISSN
0932-0776
eISSN
1865-7117
DOI
10.1515/znb-1988-0405
Publisher site
See Article on Publisher Site

Abstract

AbstractThe preparation and spectroscopic characterization of the halosulfonium salts CH3(CF3)SHal+ A-(Hal = F, Cl, Br, I, A- = AsF6-, SbF6-, SbCl 6-) is reported. The compounds are synthesized by the reaction of the sulfane CH3SCF3 with XeF+MF6-, Cl2F+AsFf6-, Cl2/AsF5, Cl2/SbCl5 , Br2/AsF5 , or I3+MF6- (M = As, Sb), resp., at low temperatures.

Journal

Zeitschrift für Naturforschung Bde Gruyter

Published: Apr 1, 1988

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