Methyl(trifluormethyl)haIogensulfonium-Salze [1] Halogen = F, CI, Br, I...
Minkwitz, Rolf; Werner, Arnulf
1988-04-01 00:00:00
AbstractThe preparation and spectroscopic characterization of the halosulfonium salts CH3(CF3)SHal+ A-(Hal = F, Cl, Br, I, A- = AsF6-, SbF6-, SbCl 6-) is reported. The compounds are synthesized by the reaction of the sulfane CH3SCF3 with XeF+MF6-, Cl2F+AsFf6-, Cl2/AsF5, Cl2/SbCl5 , Br2/AsF5 , or I3+MF6- (M = As, Sb), resp., at low temperatures.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngZeitschrift für Naturforschung Bde Gruyterhttp://www.deepdyve.com/lp/de-gruyter/methyl-trifluormethyl-haiogensulfonium-salze-1-halogen-f-ci-br-i-3JePcElKqT
AbstractThe preparation and spectroscopic characterization of the halosulfonium salts CH3(CF3)SHal+ A-(Hal = F, Cl, Br, I, A- = AsF6-, SbF6-, SbCl 6-) is reported. The compounds are synthesized by the reaction of the sulfane CH3SCF3 with XeF+MF6-, Cl2F+AsFf6-, Cl2/AsF5, Cl2/SbCl5 , Br2/AsF5 , or I3+MF6- (M = As, Sb), resp., at low temperatures.
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