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Metal oxide and bimetallic nanoparticles in ionic liquids: synthesis and application in multiphase catalysis

Metal oxide and bimetallic nanoparticles in ionic liquids: synthesis and application in... Abstract Ionic liquids (ILs) are well established as solvents and stabilizing agents for the synthesis of metallic nanoparticles (NPs) in general. The physicochemical properties of ILs and the supramolecular organization in the liquid state are capable of directing the growth of transition metal NPs generated in situ and to subsequently protect and stabilize them. Until now, many different NPs have been successfully synthesized within these media; however, the synthesis of metal oxide and bimetallic alloy or core-shell NPs in ILs is still relatively rare. Herein, we summarize the current state-of-the-art of the synthetic methods for these materials and their application in the broad field of catalysis, including multiphase systems, hydrogenation, dehydrogenation, functionalization, as well as defunctionalization reactions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nanotechnology Reviews de Gruyter

Metal oxide and bimetallic nanoparticles in ionic liquids: synthesis and application in multiphase catalysis

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References (95)

Publisher
de Gruyter
Copyright
Copyright © 2013 by the
ISSN
2191-9089
eISSN
2191-9097
DOI
10.1515/ntrev-2013-0019
Publisher site
See Article on Publisher Site

Abstract

Abstract Ionic liquids (ILs) are well established as solvents and stabilizing agents for the synthesis of metallic nanoparticles (NPs) in general. The physicochemical properties of ILs and the supramolecular organization in the liquid state are capable of directing the growth of transition metal NPs generated in situ and to subsequently protect and stabilize them. Until now, many different NPs have been successfully synthesized within these media; however, the synthesis of metal oxide and bimetallic alloy or core-shell NPs in ILs is still relatively rare. Herein, we summarize the current state-of-the-art of the synthetic methods for these materials and their application in the broad field of catalysis, including multiphase systems, hydrogenation, dehydrogenation, functionalization, as well as defunctionalization reactions.

Journal

Nanotechnology Reviewsde Gruyter

Published: Oct 1, 2013

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