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- Publisher
- de Gruyter
- Copyright
- ©2015 by De Gruyter
- ISSN
- 0932-0776
- eISSN
- 1865-7117
- DOI
- 10.1515/znb-2014-0249
- Publisher site
- See Article on Publisher Site
Abstract
AbstractVanandium trifluoride reacts with dry liquid ammonia under the formation of lilac plate-shaped crystals of mer-triammine trifluorido vanadium(III) (1), mer-[VF3(NH3)3]. Single-crystal X-ray analysis was carried out at low temperature to elucidate the structure. The compound crystallizes in the monoclinic space group P21/c with a = 5.7284(4), b = 9.2033(5), c = 10.5271(6) Å, β = 91.795(6)°, and V = 554.72(6) Å3 at 123 K with Z = 4. The discrete [VF3(NH3)3] molecules are interconnected by hydrogen bonds.
Journal
Zeitschrift für Naturforschung B – de Gruyter
Published: Mar 1, 2015