Access the full text.
Sign up today, get DeepDyve free for 14 days.
References for this paper are not available at this time. We will be adding them shortly, thank you for your patience.
AbstractThe intrinsic anharmonicity plays an important role in the thermodynamic properties of minerals at the high-temperature conditions of the mantle. To investigate the effect of iron on the thermodynamic properties of olivine, the most abundant mineral in the upper mantle, we collected in situ high-temperature and high-pressure Raman spectra of natural Fo89Fa11 and synthetic Fo58Fa42 samples. Fo58Fa42 dissociates to enstatite + quartz + Fe2O3(+Fe) at 893 K. All the Raman-active modes systematically shift to lower frequencies at elevated temperatures, whereas to higher frequencies with increasing pressure. The Ag mode at ~960 cm–1 is more sensitive to the variations of temperature and pressure than other internal modes. The crystal-field splitting of the vibrational energy states becomes slightly weakened at high temperatures but strengthened at elevated pressures. We calculated the isobaric (γiP) and isothermal (γiT) mode Grüneisen parameters for these olivine samples. The intrinsic anharmonic parameters (ai) are negative for both the lattice and internal vibrations, and our calculations indicate that the intrinsic anharmonicity makes positive contributions to the thermodynamic properties of olivine at high temperatures, such as the internal energy (U), heat capacities (CV and CP), and entropy (S). Iron incorporation further increases the magnitudes of these anharmonic contributions. In addition, the Fe effect on the intrinsic anharmonicity may also apply to other thermodynamic properties in olivine, such as equations of state and equilibrium isotopic fractionations, which are important in constraining physical and chemical properties of the upper mantle.
American Mineralogist – de Gruyter
Published: Oct 26, 2021
Keywords: Olivine; in situ high-temperature Raman; high-pressure Raman; Grüneisen parameter; intrinsic anharmonicity; thermodynamic properties
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.