Access the full text.
Sign up today, get DeepDyve free for 14 days.
C. Wentrup, Uschi Stutz, Hans-Joachim Wollweber (1978)
Synthese von Aryl‐ und Heteroarylisocyaniden aus NitrosoverbindungenAngewandte Chemie, 90
D. Chung, S. Jobic, T. Hogan, C. Kannewurf, R. Brec, J. Rouxel, M. Kanatzidis (1997)
Oligomerization Versus Polymerization of Texn- in the Polytelluride Compound BaBiTe3. Structural Characterization, Electronic Structure, and Thermoelectric PropertiesJournal of the American Chemical Society, 119
P. Böttcher (1980)
Synthesis and crystal structure of Rb2Te3 and Cs2Te3Journal of The Less Common Metals, 70
R. Hoppe (1979)
Effective coordination numbers (ECoN) and mean fictive ionic radii (MEFIR)Zeitschrift für Kristallographie - Crystalline Materials, 150
(2008)
Program for absorption correction for data from area detector frames
W. Sheldrick (2006)
CHAPTER 9.2:Polychalcogenides
Masaya Satoh, Tsuneyosi Kuroiwa (1991)
Organization of multiple nucleoids and DNA molecules in mitochondria of a human cell.Experimental cell research, 196 1
D. Santamaría-Pérez, A. Vegas, C. Muehle, Martin Jansen (2011)
Structural behaviour of alkaline sulfides under compression: high-pressure experimental study on Cs2S.The Journal of chemical physics, 135 5
B. Eisenmann, H. Schäfer (1978)
K2Te3, das erste binre Alkalimetallpolytellurid mit Te32- -IonenAngewandte Chemie
H. Sommer, R. Hoppe (1977)
Die Kristallstruktur von Cs2S. mit einer Bemerkung über Cs2Se, Cs2Te, Rb2Se und Rb2TeZeitschrift für anorganische und allgemeine Chemie, 429
P. Böttcher, J. Getzschmann, R. Keller (1993)
Zur Kenntnis der Dialkalimetalldichalkogenide β-Na2S2, K2S2, α-Rb2S2, β-Rb2S2, K2Se2, Rb2Se2, α-K2Te2, β-K2Te2 und Rb2Te2Zeitschrift für anorganische und allgemeine Chemie, 619
F. Fehér, K. Naused (1956)
Beiträge zur Chemie des Schwefels. XXVI. Über Die Systeme Rubidium—Schwefel und Caesium—SchwefelZeitschrift für anorganische und allgemeine Chemie, 283
J. Sangster, A. Pelton (1997)
The Rb-Te (rubidium-tellurium) systemJournal of Phase Equilibria, 18
I. Schewe-Miller, P. Böttcher (1991)
Synthesis and crystal structures of K5Se3, Cs5Te3 and Cs2TeZeitschrift für Kristallographie - Crystalline Materials, 196
F. Devillanova, W. Mont (2007)
Handbook of chalcogen chemistry : new perspectives in sulfur, selenium and tellurium
V. Petříček, M. Dušek, L. Palatinus (2014)
Crystallographic Computing System JANA2006: General featuresZeitschrift für Kristallographie - Crystalline Materials, 229
C. Graf, A. Assoud, Oottil Mayasree, H. Kleinke (2009)
Solid State Polyselenides and Polytellurides: A Large Variety of Se–Se and Te–Te InteractionsMolecules, 14
(2013)
Program for the Solution of Crystal Structures. University of Göttingen, Göttingen (Germany) 2013. P. Stüble et al.: Crystal structures of h.t.-Cs2S3 and K37Te28
J. McConnachie, M. Ansari, J. Bollinger, R. Salm, J. Ibers (1993)
Synthesis and structural characterization of the telluroargentate [PPh4]2[NEt4][AgTe7] and telluromercurate [PPh4]2[HgTe7] compounds containing the unprecedented .eta.3-Te74- polytelluride anionInorganic Chemistry, 32
J. Sangster, A. Pelton (1997)
The K-S (Potassium-Sulfur) systemJournal of Phase Equilibria, 18
P. Böttcher (1977)
Die Kristallstruktur von K2S3 und K2Se3Zeitschrift für anorganische und allgemeine Chemie, 432
Irmgard Schewe-Miller, P. Böttcher (1992)
Ternäre telluride mit W5Si3-Typ-Struktur: MxK4Te3 (M=Ca, Sr)☆Journal of Alloys and Compounds, 183
R. Hoppe (1979)
Effective coordination numbers (ECoN) and mean Active fictive ionic radii (MEFIR)[1,2]*Zeitschrift Fur Kristallographie, 150
W. Bues, H. Ziemann (1979)
Schwingungsspektren fester, flüssiger und gelöster Metallpolysulfide. I. Ramanspektren von Rb2S2, Rb2S3, Cs2S2 und Cs2S3Zeitschrift für anorganische und allgemeine Chemie, 456
A. Vegas, A. Grzechnik, M. Hanfland, C. Mühle, M. Jansen (2002)
Antifluorite to Ni2In-type phase transition in K2S at high pressuresSolid State Sciences, 4
T. Doert, P. Böttcher, R. Cardoso‐Gil (1999)
The Crystal Structure of Tl2Te3 – a ReinvestigationZeitschrift für anorganische und allgemeine Chemie, 625
R. Boer, E. Cordfunke (1995)
On the caesium-rich part of the CsTe phase diagramJournal of Alloys and Compounds, 228
W. Bronger, C. Bomba, J. Fleischhauer, C. Rusbüldt (1990)
Cs7Co4Se8' eine Verbindung mit [Co4Se8]-BaueinheitenJournal of The Less Common Metals, 167
I. Schewe, P. Böttcher (1990)
Darstellung und Kristallstruktur des K5Te3 / Preparation and Crystal Structure of K5Te3Zeitschrift für Naturforschung B, 45
J. Sangster, A. Pelton (1997)
The Rb-Se (Rubidium-Selenium) SystemChemInform, 28
(1976)
Parthé, Program Lazy-Pulverix
J. Sangster, A. Pelton (1997)
The Cs-Se (Cesium-Selenium) SystemChemInform, 28
(2013)
Program for the Refinement of Crystal Structures
J. McConnachie, J. Bollinger, J. Ibers (1993)
Chalcogenide substitution reactionsInorganic Chemistry, 32
P. Böttcher (1980)
Darstellung und Kristallstruktur der Dialkalimetalltrichalkogenide Rb2S3, Rb2Se3, Cs2S3 und Cs2Se3Zeitschrift für anorganische und allgemeine Chemie, 461
M. Khabachev, K. Chuntonov (1998)
Phase diagram of the system K-TeJournal of Alloys and Compounds, 265
W. Bronger, P. Böttcher (1972)
Über Thiomanganate und ‐cobaltate der schweren Alkalimetalle: Rb2Mn3S4, Cs2Mn3S4, Rb2Co3S4, Cs2Co3S4Zeitschrift für anorganische und allgemeine Chemie, 390
J. Sangster, A. Pelton (1997)
The Rb-S (Rubidium-Sulfur) SystemChemInform, 28
K. Stöwe (2004)
Polymorphic forms of Rb2Te: in-situ high-pressure DAC X-ray diffraction investigations and structure modelling with CASTEPZeitschrift für Kristallographie - Crystalline Materials, 219
A. Assoud, S. Derakhshan, N. Soheilnia, H. Kleinke (2004)
Electronic Structure and Physical Properties of the Semiconducting Polytelluride Ba2SnTe5 with a Unique Te4‐5 Unit.ChemInform, 35
J. Sangster, A. Pelton (1997)
The Cs-S (Cesium-Sulfur) SystemChemInform, 28
L. Finger, M. Kroeker, B. Toby (2007)
DRAWxtl, an open-source computer program to produce crystal structure drawingsJournal of Applied Crystallography, 40
Stefan Maier, O. Pérez, D. Pelloquin, D. Berthebaud, S. Hébert, F. Gascoin (2017)
Linear, Hypervalent Se34- Units and Unprecedented Cu4Se9 Building Blocks in the Copper(I) Selenide Ba4Cu8Se13.Inorganic chemistry, 56 15
AbstractThe high-temperature polymorph of the trisulfide Cs2S3, which has been synthesized from Cs2S2 and elemental sulfur, crystallizes in a new structure type (monoclinic, space group P21/c, a=999.97(4), b=1029.30(5), c=2642.07(12) pm, β=90.083(2)°, Z=16, R1=0.0324). The structure contains four crystallographically independent angled S32−${\rm{S}}_3^{2 - }$trisulfide ions with S–S distances of 205.7–208.3 pm. The distorted b.c.c. packing of the anions and their insertion in the five-membered rings of 3.53+3.5.3.5. (1:1) Cs nets are similarly found in the r.t. form (Cmc21, K2S3-type structure) and the two polymorphs differ mainly in the orientation of the S3 groups. The second title compound, K37Te28, was synthesized from stoichiometric melts of the elements. It forms a complex (3+1)D modulated tetragonal structure (space group I41/amd (00σ3)s0s0, q=(0, 0, 0.5143), a=1923.22(2), c=2626.66(4) pm, Z=4, R1all=0.0837). According to K37Te28=K37[Te(1X)]8[Te(2X)2]6[Te(3X)8] the structure contains three different types of Te anions: The two crystallographically different isolated telluride anions [Te(1X)]2− are coordinated by 9/10 K+ cations. Three [Te(2X)2]2− dumbbells (dTe-Te=277.9/286.4 pm) are arranged to ‘hexamers’. The Te(31) and Te(32) atoms are located in columns of face-sharing K square antiprisms. Their z position modulation, which is accompanied by a smaller shift of the surrounding K+ cations, results in the decomposition of the [Te(3X)8]2 chain in a sequence |:Te3–Te2–Te2–Te3–Te2–Te2–Te2:| of dumbbells Te22− (dTe–Te=304 pm) and hypervalent linear trimers Te34− (dTe–Te=325 pm).
Zeitschrift für Naturforschung B – de Gruyter
Published: Jan 26, 2019
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.