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AbstractA practical and efficient synthetic route to construct a variety of 3-arylselenenyl/3-arylthio spiro[4.5]trienones was developed using Selectfluor reagent as a mild oxidant. This reaction proceeds via a sequence of electrophilic cation addition, spirocyclization and dearomatization, then offers an approach to introduce Se/S-centered cation into the C–C triple bonds. The utility of this protocol were justified by the excellent compatibility of a wide range of functional groups, good yields and scalability under mild reaction conditions.
Zeitschrift für Naturforschung B – de Gruyter
Published: Jan 27, 2022
Keywords: cation pathway; chalcogenation; N -aryl propiolamides; Selectfluor; spirocyclization
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