Access the full text.
Sign up today, get DeepDyve free for 14 days.
(1241)
Rodewald, R
A. Vermeulen, S. Ambler, G. Bumgardner, Eldon Misfeldt, Jim Thompson (1998)
The Elements
(2006)
The Crystallographic Computing System, Institute of Physics, University of Prague, Prague (Czech Republic
J. Donohue (1974)
The structures of the elements
Block- and platelet-shaped single crystals of several CeNi1-xSb1+yBi1-y phases with ZrCuSiAstype structure (space group P4=nmm) were grown from a CeNiSb precursor in bismuth fluxes. The structures of CeNiSb1.19Bi0.81, CeNi0.80Sb1.16Bi0.84 and CeNi0.75Sb1.74Bi0.26 were refined from single-crystal X-ray diffractometer data. The 2b nickel site can be fully or partially occupied, and the bismuth square nets show solid solutions with antimony. CaBe2Ge2-type CeNi2-xSb2 crystals occur as by-products of the crystal growth experiments. The structure of a CeNi1.26Sb2 crystal has been refined. The small difference of the compositions hamper phase analytical studies by powder X-ray diffraction. A polycrystalline CeNiSbBi sample showed Curie-Weiss behavior with an experimental magnetic moment of 2.56(1) μB per Ce atom, indicating purely trivalent cerium. No magnetic ordering is detected down to 2:5 K. A 121Sb Mössbauer spectrum showed an isomer shift of δ = -8.06(6)mms-1, substantiating the antimonide character.
Zeitschrift für Naturforschung B – de Gruyter
Published: Apr 1, 2014
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.