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/lp/de-gruyter/a-tetranuclear-copper-ii-complex-with-pyrazole-3-5-dicarboxylate-knnwBCoABH
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- Publisher
- de Gruyter
- Copyright
- ©2016 by De Gruyter
- ISSN
- 0932-0776
- eISSN
- 1865-7117
- DOI
- 10.1515/znb-2015-0197
- Publisher site
- See Article on Publisher Site
Abstract
AbstractA tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands (pdc3−), [Me2NH2]4[Cu4(pdc)4], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N–H···O hydrogen bonds. In addition, the electrochemical behavior was studied.
Journal
Zeitschrift für Naturforschung B – de Gruyter
Published: Apr 1, 2016