A supramolecular tetranuclear zinc(II) complex constructed from an asymmetrical Salamo-type ligand: synthesis, structure and fluorescence properties
A supramolecular tetranuclear zinc(II) complex constructed from an asymmetrical Salamo-type...
Wang, Li; Zhao, Qing; Li, Xiao-Yan; An, Gao-Xian; Dong, Wen-Kui
2017-12-20 00:00:00
AbstractThe tetranuclear Zn(II) complex, [{ZnL(μ-OAc)Zn(CH3CH2CH2OH)}2], derived from an asymmetrical Salamo-type chelate ligand H3L (5-methoxy-6′-hydroxy-2,2′-[ethanedioxybis(nitrilomethylidyne)]diphenol) has been synthesized and structurally characterized by elemental analysis, IR spectrum, X-ray crystallography, UV/Vis and fluorescence spectra. The structure is made up of four Zn(II) atoms, μ2-coordinated acetate ions and two coordinated n-propanol molecules, and forms an infinite one-dimensional supramolecular structure via intermolecular C–H···π interactions. The four Zn(II) atoms are penta-coordinated and show slightly distorted trigonal bipyramidal and tetragonal pyramidal symmetries.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngZeitschrift für Naturforschung Bde Gruyterhttp://www.deepdyve.com/lp/de-gruyter/a-supramolecular-tetranuclear-zinc-ii-complex-constructed-from-an-ROjai9BVC8
A supramolecular tetranuclear zinc(II) complex constructed from an asymmetrical Salamo-type ligand: synthesis, structure and fluorescence properties
AbstractThe tetranuclear Zn(II) complex, [{ZnL(μ-OAc)Zn(CH3CH2CH2OH)}2], derived from an asymmetrical Salamo-type chelate ligand H3L (5-methoxy-6′-hydroxy-2,2′-[ethanedioxybis(nitrilomethylidyne)]diphenol) has been synthesized and structurally characterized by elemental analysis, IR spectrum, X-ray crystallography, UV/Vis and fluorescence spectra. The structure is made up of four Zn(II) atoms, μ2-coordinated acetate ions and two coordinated n-propanol molecules, and forms an infinite one-dimensional supramolecular structure via intermolecular C–H···π interactions. The four Zn(II) atoms are penta-coordinated and show slightly distorted trigonal bipyramidal and tetragonal pyramidal symmetries.
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