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A New 1D Polyoxovanadate (Cu(en) 2 V 10 O 28 )(Cu(en) 2 (H 2 O)) 2 2H 3 BO 3 2H 2 O Containing the Rarely Non-condensed Boric acid

A New 1D Polyoxovanadate (Cu(en) 2 V 10 O 28 )(Cu(en) 2 (H 2 O)) 2 2H 3 BO 3 2H 2 O Containing... A new 1D polyoxovanadate containing boric acid (Cu(en) 2 V 10 O 28 )(Cu(en) 2 (H 2 O)) 2 2H 3 BO 3 2H 2 O (1, en=ethylenediamine) has been hydrothermally synthesized and structurally characterized. Compound 1 consists of a polyoxovanadate chain (Cu(en)2V 10 O 4- 28 )n based on the linkage of decavanadate clusters and (Cu(en) 2 ) 2+ groups, complex cations (Cu(en) 2 (H 2 O)) 2+ , free H 3 BO 3 and H 2 O molecules. The polyoxovanadates and boric acid can undergo polycondensation into various B-O-V clusters under hydrothermal conditions, but 1 is the only example of the non-condensation of polyoxovanadate and boric acid. The IR spectrum and the thermal behavior of 1 were also studied http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B de Gruyter

A New 1D Polyoxovanadate (Cu(en) 2 V 10 O 28 )(Cu(en) 2 (H 2 O)) 2 2H 3 BO 3 2H 2 O Containing the Rarely Non-condensed Boric acid

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Publisher
de Gruyter
Copyright
Copyright © 2012 by the
ISSN
0932-0776
eISSN
1865-7117
DOI
10.5560/znb.2012-0208
Publisher site
See Article on Publisher Site

Abstract

A new 1D polyoxovanadate containing boric acid (Cu(en) 2 V 10 O 28 )(Cu(en) 2 (H 2 O)) 2 2H 3 BO 3 2H 2 O (1, en=ethylenediamine) has been hydrothermally synthesized and structurally characterized. Compound 1 consists of a polyoxovanadate chain (Cu(en)2V 10 O 4- 28 )n based on the linkage of decavanadate clusters and (Cu(en) 2 ) 2+ groups, complex cations (Cu(en) 2 (H 2 O)) 2+ , free H 3 BO 3 and H 2 O molecules. The polyoxovanadates and boric acid can undergo polycondensation into various B-O-V clusters under hydrothermal conditions, but 1 is the only example of the non-condensation of polyoxovanadate and boric acid. The IR spectrum and the thermal behavior of 1 were also studied

Journal

Zeitschrift für Naturforschung B – de Gruyter

Published: Sep 1, 2012

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