A cyclic mixed-valence MoVI/MoV polyoxothiomolybdate cluster anion stabilized by a [(μ-I){Ag(PPh3)3}2]+ complex cation. Preparation and structure of [(μ-I){Ag(PPh3)3}2]2 [Mo8O8(μ-OH)2(μ-OEt)6(μ-S)8(μ3-O)4{Mo(DMF)2}] · 2EtOH
A cyclic mixed-valence MoVI/MoV polyoxothiomolybdate cluster anion stabilized by a...
Wei, Wei; Xin, Zhifeng; Shi, Hua-Tian; Jia, Ai-Quan; Zhang, Qian-Feng
2015-08-01 00:00:00
AbstractTreatment of (NMe4)2[Mo2O2S6] with Ag(PPh3)3I in the presence of NaOEt in DMF/EtOH resulted in the formation of a novel MoVI/MoV polyoxothiomolybdate cluster compound [(μ-I){Ag(PPh3)3}2]2[Mo8O8(μ-OH)2 (μ-OEt)6(μ-S)8(μ3-O)4{Mo(DMF)2}] · 2EtOH. The cyclic cluster polyanion consists of an octamer {Mo8O8(μ-OH)2(μ-OEt)6 (μ-S)8(μ3-O)4} that encapsulates a central {MoVI(DMF)2 (μ3-O)4} octahedron.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngZeitschrift für Naturforschung Bde Gruyterhttp://www.deepdyve.com/lp/de-gruyter/a-cyclic-mixed-valence-movi-mov-polyoxothiomolybdate-cluster-anion-4BSVcy07yB
A cyclic mixed-valence MoVI/MoV polyoxothiomolybdate cluster anion stabilized by a [(μ-I){Ag(PPh3)3}2]+ complex cation. Preparation and structure of [(μ-I){Ag(PPh3)3}2]2 [Mo8O8(μ-OH)2(μ-OEt)6(μ-S)8(μ3-O)4{Mo(DMF)2}] · 2EtOH
AbstractTreatment of (NMe4)2[Mo2O2S6] with Ag(PPh3)3I in the presence of NaOEt in DMF/EtOH resulted in the formation of a novel MoVI/MoV polyoxothiomolybdate cluster compound [(μ-I){Ag(PPh3)3}2]2[Mo8O8(μ-OH)2 (μ-OEt)6(μ-S)8(μ3-O)4{Mo(DMF)2}] · 2EtOH. The cyclic cluster polyanion consists of an octamer {Mo8O8(μ-OH)2(μ-OEt)6 (μ-S)8(μ3-O)4} that encapsulates a central {MoVI(DMF)2 (μ3-O)4} octahedron.
To get new article updates from a journal on your personalized homepage, please log in first, or sign up for a DeepDyve account if you don’t already have one.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.