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M. Kaiser, B. Dawson, C. Barton, M. Botelho (2010)
Understanding Potential Exposure Sources of Perfluorinated Carboxylic Acids in the WorkplaceAnnals of Occupational Hygiene, 54
C. O’Dowd, M. Facchini, F. Cavalli, D. Ceburnis, M. Mircea, S. Decesari, S. Fuzzi, Y. Yoon, J. Putaud (2004)
Biogenically driven organic contribution to marine aerosolNature, 431
M. Mochida, Y. Kitamori, K. Kawamura, Y. Nojiri, Keisuke Suzuki (2002)
Fatty acids in the marine atmosphere: Factors governing their concentrations and evaluation of organic films on sea‐salt particlesJournal of Geophysical Research, 107
N. Mahowald, J. Lamarque, X. Tie, E. Wolff (2006)
Sea-salt aerosol response to climate change: Last Glacial Maximum, preindustrial, and doubled carbon dioxide climatesJournal of Geophysical Research, 111
J. Armitage, I. Cousins, R. Buck, Konstantinos Prevedouros, M. Russell, M. MacLeod, S. Korzeniowski (2006)
Modeling global-scale fate and transport of perfluorooctanoate emitted from direct sources.Environmental science & technology, 40 22
A. Holm, S. Wilson, P. Molander, E. Lundanes, T. Greibrokk (2004)
Determination of perfluorooctane sulfonate and perfluorooctanoic acid in human plasma by large volume injection capillary column switching liquid chromatography coupled to electrospray ionization mass spectrometry.Journal of separation science, 27 13
A. Middlebrook, D. Murphy, D. Thomson (1998)
Observations of organic material in individual marine particles at Cape Grim during the First Aerosol Characterization Experiment (ACE 1)Journal of Geophysical Research, 103
Hultin K. A. H. Nilsson E. D. Krejci R. Mårtensson M. E. Ehn M. Hagström Å. de Leeuw G.
In situ laboratory sea spray production during the MAP 2006 cruise on the North East Atlantic.
T. Wallington, M. Hurley, J. Xia, D. Wuebbles, S. Sillman, A. Ito, J. Penner, D. Ellis, Jonathan Martin, S. Mabury, O. Nielsen, M. Andersen (2006)
Formation of C7F15COOH (PFOA) and other perfluorocarboxylic acids during the atmospheric oxidation of 8:2 fluorotelomer alcohol.Environmental science & technology, 40 3
C. Messa, B. Sesta (1987)
Micelles in perfluorinated surfactant solutionsThe Journal of Physical Chemistry, 91
Y. Shinozuka, A. Clarke, S. Howell, V. Kapustin, B. Huebert (2004)
Sea-salt vertical profiles over the Southern and tropical Pacific oceans : Microphysics, optical properties, spatial variability, and variations with wind speedJournal of Geophysical Research, 109
Ling Li, Zushun Xu, G. Song (2009)
Study on the Langmuir aggregation of fluorinated surfactants on proteinJournal of Fluorine Chemistry, 130
Armitage J. M. MacLeod M. Cousins I. T.
Comparative assessment of the global fate and transport pathways of long-chain perfluorocarboxylic
Kim Hultin, E. Nilsson, R. Krejci, E. Mårtensson, M. Ehn, Å. Hagström, G. Leeuw (2010)
In situ laboratory sea spray production during the Marine Aerosol Production 2006 cruise on the northeastern Atlantic OceanJournal of Geophysical Research, 115
Eva Webster, D. Ellis (2010)
Potential role of sea spray generation in the atmospheric transport of perfluorocarboxylic acidsEnvironmental Toxicology and Chemistry, 29
D. Ellis, Jonathan Martin, S. Mabury, M. Hurley, M. Andersen, T. Wallington (2003)
Atmospheric lifetime of fluorotelomer alcohols.Environmental science & technology, 37 17
V. Jokinen, J. Mäkelä (1997)
Closed-loop arrangement with critical orifice for DMA sheath/excess flow systemJournal of Aerosol Science, 28
S. Benassai, S. Becagli, R. Gragnani, O. Magand, M. Proposito, I. Fattori, R. Traversi, R. Udisti (2005)
Sea-spray deposition in Antarctic coastal and plateau areas from ITASE traversesAnnals of Glaciology, 41
Kim Hultin, R. Krejci, Jarone Pinhassi, Laura Gómez-Consarnau, E. Mårtensson, Å. Hagström, E. Nilsson (2011)
Aerosol and bacterial emissions from Baltic SeawaterAtmospheric Research, 99
D. Ellis, Jonathan Martin, Amila Silva, S. Mabury, M. Hurley, M. Andersen, T. Wallington (2004)
Degradation of fluorotelomer alcohols: a likely atmospheric source of perfluorinated carboxylic acids.Environmental science & technology, 38 12
M. Houde, Jonathan Martin, R. Letcher, K. Solomon, D. Muir (2006)
Biological monitoring of polyfluoroalkyl substances: A review.Environmental science & technology, 40 11
M. Bernett, W. Zisman (1959)
Wetting of Low-Energy Solids by Aqueous Solutions of Highly Fluorinated Acids and SaltsThe Journal of Physical Chemistry, 63
C. O’Dowd, B. Langmann, S. Varghese, C. Scannell, D. Ceburnis, M. Facchini (2008)
A combined organic‐inorganic sea‐spray source functionGeophysical Research Letters, 35
H. Scholberg, R. Guenthner, R. Coon (1953)
Surface Chemistry of Fluorocarbons and their DerivativesThe Journal of Physical Chemistry, 57
(2001)
Fluorinated Surfactants and Repellents, 2nd edn 2001 (Markel Dekker: New York)
Tyree C. A. Hellion V. M. Alexandrova O. A. Allen J. O.
Foam droplets generated from natural and artificial seawaters.
Burns D. C. Ellis D. A. Li H. McMurdo C. J. Webster E.
Experimental p K a determination for perfluorooctanoic
H. Klevens (1958)
Association in fluoroacids. Spectral charakteristics of added dyesKolloid-Zeitschrift, 158
R. Gershey (1983)
Characterization of seawater organic matter carried by bubble‐generated aerosols1Limnology and Oceanography, 28
Colin McMurdo, D. Ellis, Eva Webster, J. Butler, Rebecca Christensen, Liisa Reid (2008)
Aerosol enrichment of the surfactant PFO and mediation of the water--air transport of gaseous PFOA.Environmental science & technology, 42 11
J. Tolls, D. Sijm (2000)
Estimating the Properties of Surface-Active Chemicals
David Slauenwhite, Bruce Johnson (1999)
Bubble shattering : Differences in bubble formation in fresh water and seawaterJournal of Geophysical Research, 104
H. Arp, K. Goss (2008)
Irreversible sorption of trace concentrations of perfluorocarboxylic acids to fiber filters used for air samplingAtmospheric Environment, 42
N. Yamashita, K. Kannan, S. Taniyasu, Y. Horii, G. Petrick, T. Gamo (2005)
A global survey of perfluorinated acids in oceans.Marine pollution bulletin, 51 8-12
H. Struthers, A. Ekman, P. Glantz, T. Iversen, A. Kirkevåg, E. Mårtensson, Ø. Seland, E. Nilsson (2010)
The effect of sea ice loss on sea salt aerosol concentrations and the radiative balance in the ArcticAtmospheric Chemistry and Physics, 11
J. Armitage, M. MacLeod, I. Cousins (2009)
Comparative assessment of the global fate and transport pathways of long-chain perfluorocarboxylic acids (PFCAs) and perfluorocarboxylates (PFCs) emitted from direct sources.Environmental science & technology, 43 15
C. O’Dowd, G. Leeuw (2007)
Marine aerosol production: a review of the current knowledgePhilosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 365
E. Fuentes, H. Coe, D. Green, G. Leeuw, G. Mcfiggans (2009)
Laboratory-generated primary marine aerosol via bubble-bursting and atomizationAtmospheric Measurement Techniques, 3
A. Marcomini, G. Pojana, A. Giacometti, C. Oppo (2001)
Aerosolization of an anionic surfactant (LAS) and dissolved organic carbon (DOC) under laboratory conditions.Chemosphere, 44 2
NakayamaHaruo (1967)
The Effect of Added Salts on the Solubilities and Krafft Points of Sodium Dodecyl Sulfate and Potassium Perfluoro-octanoateBulletin of the Chemical Society of Japan, 40
Konstantinos Prevedouros, I. Cousins, R. Buck, S. Korzeniowski (2006)
Sources, fate and transport of perfluorocarboxylates.Environmental science & technology, 40 1
K. Sellegri, C. O’Dowd, Y. Yoon, S. Jennings, G. Leeuw (2006)
Surfactants and submicron sea spray generationJournal of Geophysical Research, 111
Armitage J. M. Macleod M. Cousins I. T.
Modeling the global fate and transport of perfluorooctanoic
J. Armitage, M. MacLeod, I. Cousins (2009)
Modeling the global fate and transport of perfluorooctanoic acid (PFOA) and perfluorooctanoate (PFO) emitted from direct sources using a multispecies mass balance model.Environmental science & technology, 43 4
H. Klevens, M. Raison (1954)
Association dans les perfluoroacides: III. Etudes des tensions superficiellesJournal of Computers, 51
M. McLachlan, K. Holmstrom, M. Reth, U. Berger (2007)
Riverine discharge of perfluorinated carboxylates from the European continent.Environmental science & technology, 41 21
K. Shinoda, H. Nakayama (1963)
Separate determinations of the surface excesses of surface-active ions and of gegenions at the air-solution interfaceJournal of Colloid Science, 18
E. Psillakis, Jie Cheng, M. Hoffmann, A. Colussi (2009)
Enrichment factors of perfluoroalkyl oxoanions at the air/water interface.The journal of physical chemistry. A, 113 31
X. Ju, Yihe Jin, K. Sasaki, N. Saito (2008)
Perfluorinated surfactants in surface, subsurface water and microlayer from Dalian Coastal waters in China.Environmental science & technology, 42 10
Wen Guo, T. Brown, B. Fung (1991)
Micelles and aggregates of fluorinated surfactantsThe Journal of Physical Chemistry, 95
M. Facchini, M. Rinaldi, S. Decesari, C. Carbone, E. Finessi, M. Mircea, S. Fuzzi, D. Ceburnis, R. Flanagan, E. Nilsson, G. Leeuw, M. Martino, J. Woeltjen, C. O’Dowd (2008)
Primary submicron marine aerosol dominated by insoluble organic colloids and aggregatesGeophysical Research Letters, 35
E. Mårtensson, E. Nilsson, G. Leeuw, L. Cohen, H. Hansson (2003)
Laboratory simulations and parameterization of the primary marine aerosol productionJournal of Geophysical Research, 108
W. Keene, H. Maring, J. Maben, D. Kieber, A. Pszenny, Elizabeth Dahl, Miguel Izaguirre, Andrew Davis, Michael Long, Xianliang Zhou, L. Smoydzin, R. Sander (2007)
Chemical and physical characteristics of nascent aerosols produced by bursting bubbles at a model air-sea interfaceJournal of Geophysical Research, 112
Marcomini A. Pojana G. Giacometti A. Oppo C.
Aerosolization of an anionic
D. Burns, D. Ellis, Hongxia Li, Colin McMurdo, Eva Webster (2008)
Experimental pKa determination for perfluorooctanoic acid (PFOA) and the potential impact of pKa concentration dependence on laboratory-measured partitioning phenomena and environmental modeling.Environmental science & technology, 42 24
J. Allen, C. Tyree (2007)
Mass flux and ionic composition of foam droplets generated from natural and artificial seawaters
Wallington T. J. Hurley M. D. Xia J. Wuebbles D. J. Sillman S. Ito A. Penner J. E. Ellis D. A. Martin J. Mabury S. A. Nielsen O. J. Andersen M. P. S.
Formation of C 7 F 15
Environmental context Perfluorinated alkyl acids are found in the remotest parts of the world, but it is still not known how they get there. By using a laboratory sea spray simulator, it is shown that these compounds are efficiently transferred from water to air. This indicates that perfluorinated alkyl acids could be transported long distances as a result of breaking waves ejecting them into the atmosphere. Abstract One hypothesis for the origin of perfluorinated alkyl acids, their salts and conjugate bases (here collectively termed PFAAs) in the atmosphere is transfer from the surface ocean by sea spray, the mechanistic explanation being that the surface active properties of PFAAs result in their enrichment on the surface of bursting bubbles. The water-to-air transfer of C 6 –C 14 perfluorocarboxylates (PFCAs) and C 6 , C 8 and C 10 perfluorosulfonates (PFSAs) was studied in a laboratory scale sea spray simulator containing tap water spiked with PFCAs and PFSAs. The sequestration of the PFAAs out of bulk water and to the air–water surface was shown to increase exponentially with the length of the perfluorinated alkyl chain. Volatilisation of the PFAAs from an aqueous solution in the absence of spray resulted in less than 1 % transfer to the atmosphere during the experiment. In the presence of spray the transfer rate from water to air increased by up to 1360 times. The enhancement was dependent on the PFAA chain length, with the C 6 carboxylate showing an enhancement of a factor of 37, the C 7 carboxylate an enhancement of 320, whereas for all remaining PFAAs the enhancement exceeded 450 with the exception of the C 14 carboxylate (106).
Environmental Chemistry – CSIRO Publishing
Published: Aug 19, 2011
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