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A one-pot synthesis of random multiblock copolymers of norbornene and cyclooctene was performed for the first time. It was shown that the first-generation Grubbs Ru–carbene complex enables the synthesis of these copolymers directly from monomers. The one-pot synthesis starts with the metathesis...
Dipinodiazafluorenes are hybrid nopinane-annelated heterocycles whose molecules include a heterocyclic core of 4,5-diazafluorene fused with fragments of terpene hydrocarbon; they can selectively extract palladium (88−100%), gold (42−96%), and ruthenium (8−19%) by single extraction from acidic...
New 1,5,3,7-diazadiphosphacyclooctanes with N,O-, N,N-, N,S-, and N,N,S-heterocyclic substituents at the nitrogen atoms have been synthesized. The influence of the nature of amines containing sp2-hybridized nitrogen atom in the ortho-position of the heterocyclic substituent on the result of...
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