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The effect of an increase in the electron density in silver nanoparticles during their formation through photochemical reduction of Ag+ ions in the presence of oxalate has been discovered and substantiated. The effect causes a shift of the of localized surface plasmon resonance (SPR) band from...
The reaction of [3 + 2] cycloaddition of a lappaconitine-based nitrone with N,N-diethylallylamine is accompanied by the formation of two minor products, unusual for the reaction of this type, containing the pyrrole cycle. The structures of the products have been established from the data of 1H...
It has been shown that the difference in the structure of electronic orbitals of silicon and germanium atoms is a decisive factor responsible for the formation of porous layers during their electrochemical etching in solutions of hydrofluoric acid.
It was experimentally shown for the first time that compact samples of pyrophoric nickel nanopowders can be passivated in air for 3–5 s. The passivation of the samples was confirmed by the absence of noticeable heat release during slow heating to 200°C, an insignificant oxygen content according...
The reaction of Sovol technical-grade mixture of polychlorinated biphenyls with sodium methoxide in dimethyl sulfoxide and ethanol medium has been studied for the first time by thermodynamic modeling. The addition of ethanol co-solvent to dimethyl sulfoxide has been found to result in the...
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