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Biphenylene bridged bisaroyl‐S,N‐ketene acetals can be readily synthesized by a one‐pot Masuda borylation‐Suzuki arylation sequence, thus, yielding a library of 20 bisaroyl‐S,N‐ketene acetals with tunable solid‐state emission and aggregation‐induced enhanced emission characteristics depending on...
Deep understanding of the inherent luminescence mechanism is essential for the development of aggregation‐induced emission (AIE) materials and applications. We first note that the intermolecular excitonic coupling is much weaker in strength than the intramolecular electron‐vibration coupling for...
A rich variety of smart materials developed via supramolecular assembly strategies have been introduced in the past decades. However, most materials reside in the thermodynamic equilibrium state, opposed to those nonequilibrium structures with sophisticated functions that are observed in living...
π‐Conjugated organic/polymer materials‐based solar cells have attracted tremendous research interest in the fields of chemistry, physics, materials science, and energy science. To date, the best‐performance polymer solar cells (PSCs) have achieved power conversion efficiencies exceeding 18%,...
Chiral structures not only exist in nature widely, they also emerge in artificial systems, attracting myriad attentions due to their excellent mechanical, optical, electrical, and magnetic properties. Self‐assembly of chiral block copolymers (BCPs*), where at least one block consists of chiral...
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