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Main Group Metal Chemistry Volume 41 Issue 5-6

Subject Areas: Chemistry (miscellaneous)
Publisher: De Gruyter - de Gruyter
ISSN: 2191-0219
SJR: 25

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Frontmatter

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-frontmatter5-6
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Journal Article

Synthesis and structural characterization of neutral hexacoordinate silicon(IV) complexes containing salophen and thiocyanato-N ligands

González-García, Gerardo; Pérez, Astrid; López, Jorge A.; Puello-Polo, Esneyder; González-García, Andrés

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2017-0053

AbstractThe reaction of the H2salophen ligand, 2,2′-((1E,1′E)-(1,2-phenylenebis(azanylylidene))bis (methanylylidene))diphenol, with one molar equivalent of Si(NCS)4, MeSi(NCS)3 (13), or HMeSi(NCS)2 afforded neutral hexacoordinate silicon complexes, which have an-NCS bi-functionality (complex 1)...
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Bismuth(III) bromide-thioamide complexes: synthesis, characterization and cytotoxic properties

Cakmak, M.; Ozturk, I.I.; Banti, C.N.; Manoli, M.; Moushi, E.; Tasiopoulos, A.J.; Grześkiewicz, A.M.; Kubicki, M.; Hadjikakou, S.K.

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-0035

AbstractNew bismuth(III) bromine compounds of the heterocyclic thioamides were prepared and structurally characterized. The reaction of heterocyclic thioamides with bismuth(III) bromide resulted in the formation of the {[BiBr2(μ2-Br)(MMI)2]2·CH3COCH3·H2O} (1), {[BiBr2(MBZIM)4]·Br·2H2O} (2),...
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Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Liu, Jin; Liu, Min; Wang, Shiqing; Li, Yuxiao; Liu, Mingzhu; Wang, Yue; Tian, Laijin; Liu, Xicheng

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-0031

AbstractThree bis(triorganotin) benzenedicarboxylates, 1,n-C6H4(COOSnR3)2 (n, R=3, C6H5C(CH3)2CH2, 1; 4, C6H5C(CH3)2CH2, 2; 4, C6H11-c, 3), were synthesized by the reaction of 1,3 or 1,4-benzenedicarboxylic acid with triorganotin chlorides in the solution of CH3ONa-CH3OH and characterized by...
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Two new Mg3(II)-cluster-based coordination polymers: their synthesis, crystal structures and inhibiting activity on the human spinal tumor cells

Ji, Qing; Zhu, Jiang; Jin, Hui; Zhan, De-Ping; Huang, Jie

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-0022

AbstractIn this study, two new Mg3-cluster-based coordination polymers are obtained via a one-pot solvothermal reaction of Mg(NO3)2·6H2O with two C3-symmetrical N-rich polycarboxylic acid organic ligands with different ligand flexibilities, which show interesting structural diversity. The complex...
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Response surface methodological approach for optimizing the removal of cadmium from aqueous solutions using pistachio residues biochar supported/non-supported by nanoscalezero-valent iron

Saffari, Mahboub

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-0011

AbstractA three-level Box–Behnken model (BBM) under response surface methodology (RSM) was used to optimize the removal of cadmium (Cd) ion by pistachio residues biochar (PRB) and PRB supported by nanoscale zero-valent iron (PRB-nZVI) from aqueous solutions. Optimization experiments were carried...
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Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative

Diallo, Waly; Diop, Libasse; Diop, Cheikh Abdoul Khadir; Cattey, Hélène; Plasseraud, Laurent

2018 Main Group Metal Chemistry

doi:10.1515/mgmc-2018-0029

AbstractThe polymeric organotin(IV) selenate complex [(Me3Sn)3(SeO4)(OH)]n (1) has been isolated as single crystals from the reaction of [(Me2NH2)2SeO4] and Me3SnCl in methanol. In the solid state, compound 1 was characterized by X-ray diffraction analysis, Fourier transform-infrared...

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